Reagents for diverse iodosilane-mediated transformations.
نویسندگان
چکیده
It was observed that a PhSiH2I-mediated protocol using PhSiH3 and cat. I2 caused the deiodination of 2-(iodomethyl)-2-phenyltetrahydrofuran. Stemming from the investigation of the mechanism, we found that the PhSiH3-I2 system selectively promotes diverse cascade transformations from cyclic ethers to acyclic alkyl iodides, and the PhSiH3-N-iodosuccinimide (NIS) system also promotes cascade transformations from cyclic ethers to acyclic alcohols.
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 14 23 شماره
صفحات -
تاریخ انتشار 2016